Cryogenic Processing of Metals

Using More of the Temperature Range

Cryogenic Processing of Metals is also known as Deep Cryogenic Treatment, DCT for short. DCT is an effective means of increasing industrial plant efficiency, increasing quality, and making products superior to competing products and making components perform better and last longer. DCT is a process that helps finish the heat treat that now is usually stopped at room temperature or slightly below.

We live in a very narrow temperature range between approximately -40o and 130oF. That is the temperature range in which we lived for thousands of years. Then we discovered fire and found that high temperatures were successful in helping us change materials. Fire helped us soften and harden metals. Fire helped us melt metals so we could shape them by casting. The effects of heat on metals and other materials were visible or easily detectable. A hardened piece resisted scratching and bending more. An annealed piece could be worked easier. A melted piece was liquid. Fire helped us turn metal ore into metallic form.

The lower temperature limit in the processing of metals stopped at a temperature in the life sustaining zone, and usually at ambient temperature for the day. Yes, the Swiss would bury watch parts in the snow to improve their wear resistance, and casting companies (and racers) would let castings “age” outside for long periods of time. They found that the aged castings did not distort so much in machining and in use and did have some better wear resistance. But there were big obstacles to using cold temperatures for treating metals. One was that until the late 1800’s it just wasn’t possible to get a lot of cold. The other was that people couldn’t conceive that a change could be made in a ‘frozen’ piece of metal.

It was the late 1800’s when people started to find ways of liquefying air. At first the amount that they could liquefy was extremely small. By the first decade of the 1900’s companies started to make liquid oxygen and liquid nitrogen in ‘industrial’ quantities. It took a while for them to get past freezing flowers and small animals. After all, what do you do with something you have never had before? Initial results on some metals that were dropped into liquid nitrogen produced negative effects.

Metallurgists were learning more about metals about this time. This was a time when metallurgists started polishing and etching metal samples and looking at them under a microscope. In steels they found that there were different ways the iron atoms related to the carbon atoms and the alloying atoms related to each other depending on the thermal history in both temperature and time of the part. You see, metals are crystalline. The way the atoms relate to each other depends on how hot or cold they have been and how fast the temperature changed. Crystal structure is what gives metals their metallic characteristics. So when someone tells you that a part failed because the metal crystallized you automatically know they do not know what they are talking about.   By the way, metals are not molecular. So when someone tells you DCT affects the molecular structure of the metal you also know that they do not know what they are talking about.

A hard form of steel is called Martensite. Martensite was named after Adolph Martens, a German metallurgist who lived from 1850 to 1914. It has a distinctive structure when magnified. It is produced by heating steel to a high temperature. At that temperature (which is alloy dependent), the steel forms a structure named Austenite. Austenite is named for British metallurgist Sir William Chandler Roberts-Austen. When austenite is cooled quickly from its formation temperature, it forms Martensite. If it is cooled slowly, it remains Austenite. Cool it at some intermediate rate and some martensite forms but some austenite will remain. The remaining austenite is referred to as retained austenite. It turns out that if you bring the temperature way down, retained austenite will turn into martensite. Also, you can vibrate or cold work or temper (tempering is a mild heating process) or just age retained austenite and it will transform to martensite.

Certain things happen when transforming austenite to martensite. First, martensite is bigger because the atoms are farther away from one another. So the part grows. It doesn’t always grow evenly because metal grains are not all lined up evenly. This means the part can also warp. Also martensite needs to be tempered or it will be brittle. Now here is the kicker. If you have retained austenite (and you will) your part will change size, warp and have brittle areas because vibration, temperature change in use, and you cannot stop the passage of time. So tightly toleranced parts can change size and to some extent shape in use. This can make them unsuitable for use or require them to be designed with looser tolerances than ideal to allow for the change. A good example of this is with ejector pins in plastics molds. They have to have a close fit in order to reduce the possibility of the plastic going between the pin and the pin bore. We’ve found they can grow in use and then start to scrape and gall. DCT stops this.

Another problem with heat treated parts is that they can have residual stresses built up through the heat treat. Again, heat and vibration can release these stresses and cause warping and dimensional change. DCT relieves residual stresses and reduces this affect.

Besides transforming retained austenite, cold has other effects on crystal structure. It affects the concentration of point defects in the metal. For instance, the number of vacancies in the crystal matrix (areas where an atom should be but is not) are temperature dependent. The higher the temperature, the more vacancies can exist. Cold reduces the number of vacancies. It makes the atom to atom distance more uniform and more ideal. It affects where the alloying elements are in the crystal matrix. All these happen for reasons that are beyond the scope of this article, but are taught in the primary courses in metallurgy.

DCT offers a definite finish for heat treating through the use of more of the temperature range. We call that range cold only because it feels cold to humans, it is outside the temperature range that we are used to. It removes residual stresses, stabilizes materials, improves wear resistance, and increases fatigue life.